Silver-catalyzed furoquinolines synthesis: from nitrogen effects to the use of silver imidazolate polymer as a new and robust silver catalyst.
نویسندگان
چکیده
Silver-catalyzed tandem acetalization and cycloisomerization reactions were found to lead to various furoquinolines, and a nitrogen effect was noticed for AgOTf reactivity, since the cyclization mode switched from 6-endo-dig to 5-exo-dig; from these observations silver imidazolate polymer is proposed as a stable silver catalyst.
منابع مشابه
Synthesis and reactivity of furoquinolines bearing an external methylene-bond: access to reduced and spirocyclic structures.
A family of furoquinolines were efficiently obtained through a tandem acetalization/cycloisomerization process catalyzed by (5 mol%) silver imidazolate polymer and triphenylphosphine, and diversity was brought by the use of 7 different alcohol groups. From these furoquinolines, 3 examples of reduced derivatives could be obtained (d.r. up to 94 : 6), 10 different spiroketal derivatives by hetero...
متن کاملSynthesis and characterization of Polyvinyl Alcohol-Polypyrrole-Silver nanocomposite polymer films
The present paper describes the preparation and characterization of Polyvinyl Alcohol-Polypyrrole-Silver Nanocomposite (PVA-PPy-Ag NC) films. The prepared films were conducting, freestanding, flexible, and robust. Silver nanoparticles (Ag NPs) were synthesized from an aqueous solution of silver nitrate using trisodium citrate as a reductant. The casting solution for the films was prepared by in...
متن کاملSynthesis of Silver Nanoparticles from Spent X-Ray Photographic Solution via Chemical Rreduction
Silver metal was recovered primarily from spent X-ray photographic solution using a horizontal tube furnace. The X-Ray Diffraction (XRD) spectroscopy analysis approved almost 95 percent purity of the recovered silver metal. In the next step, the synthesis of silver nanoparticles from the recovered silver metal proceeded by using chemical reduction method. The proposed method uses e...
متن کاملGreen Synthesis of Silver Nanoparticles with Allium paradoxum Extract and Evaluation of their Antibacterial Activities
Background and purpose: Microbial resistance against antibiotics is increasingly growing, therefore, it is necessary to develop new remedies. Silver nanoparticles have significant antibacterial properties and synthesis of silver nanoparticles mediated by plant extracts could be considered as an alternative in treatment in various infections. Materials and methods: In this study, silver nano...
متن کاملGreen bio-synthesis of Silver Nanoparticles Using Ziziphora tenuior L Water Extract
Different biological methods are gaining recognition for the production of silver nanoparticles (Ag-NPs) due to their multiple applications. The use of plants in the synthesis of nanoparticles emerges as a cost effective and eco-friendly approach. In the present study, the synthesis of silver nanoparticles by using Ziziphora tenuior L of water extraction was carried out. For this purpose the wa...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 47 1 شماره
صفحات -
تاریخ انتشار 2011